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. 2016 Nov 8;1(5):854–867. doi: 10.1021/acsomega.6b00237

Table 1. Oxidation (EpOx) and Reduction (EpRed) Potentials of Complexes 4 and 5 at a Pt Electrodea.

compound EpOx, V EpRed1, V EpRed2, V
4c 1.30 –0.75 –1.08
4b 1.35 –0.74 –1.09
5b 1.32 –0.65 –0.98
5c 1.32 –0.78 –1.15
4eb     –1.18
5ec 1.81 –0.87 –2.46
a

DMF, Bu4NBF4, Ag/AgCl, KClsat, 20 °C, 100 mV s–1 scan rate.

b

Cu (2e–2H).19

c

Cu (3e–2H).19