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. 2017 Feb 27;2(2):698–711. doi: 10.1021/acsomega.6b00509

Table 2. Isomerization of Substituted 2-(3-Butenyl)-benzoic Acids.

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entry R, reactant product yield (%)a
1 3-CH3, 2a 2b 76
2 4-CH3, 3a 3b 85
3 5-CH3, 4a 4b 81
4 6-CH3, 5a 5b 83
5 4-F, 6a 6b 79
6 5-F, 7a 7b 56
7 4-Cl, 8a 8b 92
8 5-Cl, 9a 9b 97
9 3-OMe, 10a 10b 30
10 4-OMe, 11a 11b 97
11 6-OMe, 12a 12b 81
12 3-NO2, 13a 13b 0
13 4-OH, 6-OH, 14a 14b 0
14 4-OAc, 6-OAc, 15a 15b 92
a

Isolated yield.