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. 2017 Feb 27;2(2):698–711. doi: 10.1021/acsomega.6b00509

Table 4. Recycling Studies for the Isomerization Reaction of 1a.

  trial 1,a yield (%)b trial 2,c yield (%)b trial 3,d yield (%)b
cycle 1 81 81 80
cycle 2 68 78 74
cycle 3 64 29 72
cycle 4 0 2 24
a

PdCl2 (5 mol %); reactions conducted in CH2Cl2 at 25 °C for 5 h for each cycle. All operations were under an atmosphere of N2.

b

Isolated yield of 1b.

c

PdCl2 (10 mol %); reactions conducted in CH2Cl2 at 25 °C for 5 h for each cycle.

d

PdCl2 (20 mol %); reactions conducted in CH2Cl2 at 25 °C for 2 h for each cycle.