Table 2. Reaction at the Membrane Interior or Intermembrane.
| entry | amphiphile (assembly) | medium | conv. (%) | e.e. (%) (S–R) |
|---|---|---|---|---|
| Va | CTAB (micelle) | water | 92 ± 4 | 4 ± 2 |
| VIb | DOPC (liposome) | water | 56 ± 8 | 92 ± 2 |
| VIIc | DOPC | water | <2 | n.d.e |
| VIIId | DOPC | water | 11 ± 2 | >90 |
1-Adsorbed CTAB micelle and 2-adsorbed CTAB micelle suspensions were mixed to initiate the reaction.
1 was added to 2-adsorbed DOPC liposome suspension to initiate the reaction.
1-Adsorbed DOPC liposome and 2-adsorbed DOPC liposome suspensions were mixed to initiate the reaction.
The reaction was conducted for 9 h at r.t.
Not detected.