Skip to main content
. 2017 Feb 10;2(2):487–495. doi: 10.1021/acsomega.7b00028

Table 3. Screening of Palladium Complexesa.

graphic file with name ao-2017-000285_0008.jpg

      yield (%)b
entry Pd complex time (h) 2a 4 recovered 1
1 (MeCN)2PdCl2 2 69 (64)c 0 0
2 (Ph3P)2PdCl2 23.5 0 0 99
3 PdCl2 23.5 30 0 51
4 (PhCN)2PdBr2 1 70 0 0
5 Pd(OAc)2 22.5 0 5 83
6 Pd(OCOCF3)2 22.5 0 71 0
7 Pd(PPh3)4 16 0 0 >99
8 Pd2(dba)3·CHCl3 16 0 0 >99
a

All reactions were conducted with 0.194 mmol of 1 in DME (1.0 mL).

b

Determined by 1H NMR analysis using an internal standard.

c

Isolated yield is given in parentheses.