. 2018 Jan 24;3(1):863–871. doi: 10.1021/acsomega.7b01688

Table 6. Effect of the Catalyst Loading on the Reaction Efficiency [Yields, Isomeric Content (α/β Ratio) and TONs]^a^,^b.

		yields, isomeric ratio, and TON under selected conditions
entry	catalyst loading, mol %	80 °C/6 h	100 °C/4 h
1–2	1	83 (17/83) 83	82 (17/83) 82
3–4	0.1	90 (19/81) 900	85 (48/52) 850
5–6	0.01	85 (68/32) 8500	77 (68/32) 7700
7–8	0.001	9 (64/36) 9000	7 (62/38) 7000
9–10	0.0001	<5	<5

PhC≡CH (5.0 × 10^–4 mol, 1 equiv), Et₃SiH (5.0 × 10^–4 mol, 1 equiv), catalyst 18; toluene (0.5 mL).

Yields of products were determined by ¹H NMR spectroscopy using 1,2-dimethoxyethane as the standard, whereas the isomeric content was determined on the basis of the alkene coupling constants.

Table 6. Effect of the Catalyst Loading on the Reaction Efficiency [Yields, Isomeric Content (α/β Ratio) and TONs]a,b.

Table 6. Effect of the Catalyst Loading on the Reaction Efficiency [Yields, Isomeric Content (α/β Ratio) and TONs]^a^,^b.