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. 2018 Feb 21;3(2):2130–2140. doi: 10.1021/acsomega.7b01425

Figure 2.

Figure 2

Parabolic PESs for reactants (red) and products (blue) in an electron self-exchange process as a function of the reaction coordinate. Top: M– ↔ M. Bottom: M– + M → M + M–. ΔG† is not obtained by only the value of λI, but a new reorganization energy λII must be considered.