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. 2018 Jan 2;3(1):22–29. doi: 10.1021/acsomega.7b01642

Table 2. Experimental Cotton Effects Observed for Bromo[2.2]paracyclophanes 12a.

  1
p-2
m′-2
o′-2
band λ/nm Δε/M–1 cm–1 λ/nm Δε/M–1 cm–1 λ/nm Δε/M–1 cm–1 λ/nm Δε/M–1 cm–1
A 322 +0.1 321 +0.6 316 +1.1 316 +0.6
B 290b –2.4 290b –4.8 290b –3.3 290b –1.9
C 261 –16.8 267 –23.7 265b –28.7 262 –25.3
250b –15.5 250b –15.7 256 –31.0 255b –24.1
D 221 +24.3 228 +36.7 238 +14.4 238 +21.5
215b +19.3 215b +17.2 222 +18.0 222 +15.0
E 202 –26.7 203 –20.6 205 –33.3 205 –43.6
a

In acetonitrile at 25 °C.

b

Shoulder.