Table 2. Experimental Cotton Effects Observed for Bromo[2.2]paracyclophanes 1–2a.
1 |
p-2 |
m′-2 |
o′-2 |
|||||
---|---|---|---|---|---|---|---|---|
band | λ/nm | Δε/M–1 cm–1 | λ/nm | Δε/M–1 cm–1 | λ/nm | Δε/M–1 cm–1 | λ/nm | Δε/M–1 cm–1 |
A | 322 | +0.1 | 321 | +0.6 | 316 | +1.1 | 316 | +0.6 |
B | 290b | –2.4 | 290b | –4.8 | 290b | –3.3 | 290b | –1.9 |
C | 261 | –16.8 | 267 | –23.7 | 265b | –28.7 | 262 | –25.3 |
250b | –15.5 | 250b | –15.7 | 256 | –31.0 | 255b | –24.1 | |
D | 221 | +24.3 | 228 | +36.7 | 238 | +14.4 | 238 | +21.5 |
215b | +19.3 | 215b | +17.2 | 222 | +18.0 | 222 | +15.0 | |
E | 202 | –26.7 | 203 | –20.6 | 205 | –33.3 | 205 | –43.6 |
In acetonitrile at 25 °C.
Shoulder.