Table 7. Selected Interatomic Distances (Å) for the Tetragonal Symmetry Calculated Using PDF and for Cubic Symmetry Calculated Using Rietvelda.
method |
||||||
---|---|---|---|---|---|---|
Rietveld | ||||||
symmetry |
||||||
tetragonal | cubic | |||||
sample |
||||||
Tb:AS | Tb:HT | pure:HT | Tb:AS | Tb:HT | pure:HT | |
Y1–F1 | 2.359 (5) | 2.354 (3) | 2.354 (4) | 2.370 (1) | 2.356 (7) | 2.355 (6) |
Y1–F2 | 2.206 (3) | 2.198 (2) | 2.197 (3) | 2.194 (8) | 2.198 (5) | 2.199 (5) |
Y1–F3 | 2.122 (4) | 2.199 (2) | 2.199 (3) | |||
Y2–F1 | 2.297 (4) | 2.355 (3) | 2.354 (4) | |||
Y2–F2 | 2.237 (5) | 2.203 (4) | 2.203 (5) | |||
K1–F1 | 2.941 (5) | 2.764 (3) | 2.764 (5) | 2.711 (4) | 2.757 (2) | 2.762 (2) |
K1–F2 | 3.187 (8) | 3.197 (3) | 3.197 (4) | 3.202 (1) | 3.200 (7) | 3.199 (6) |
K1–F3 | 3.227 (4) | 3.204 (6) | 3.203 (8) |
AS and HT stand for as-synthesized and heat-treated samples, respectively.