Table 1. Observed NMR Vicinal 1H–1H Coupling Constants of E_Modela.
solvent | permittivity | temp (°C) | JHH | JHH′ |
---|---|---|---|---|
chloroform-d | 4.8 | 15 | 6.46 | 2.70 |
25 | 6.46 | 2.81 | ||
35 | 6.46 | 2.89 | ||
45 | 6.45 | 2.97 | ||
55 | 6.44 | 3.05 | ||
acetone-d6 | 20.7 | 15 | 6.52 | 2.60 |
25 | 6.49 | 2.65 | ||
35 | 6.49 | 2.70 | ||
45 | 6.48 | 2.76 | ||
methanol-d4 | 32.7 | 15 | 6.48 | 2.58 |
25 | 6.47 | 2.61 | ||
35 | 6.46 | 2.67 | ||
45 | 6.46 | 2.75 | ||
55 | 6.46 | 2.82 | ||
DMSO-d6 | 46.7 | 25 | 6.49 | 2.48 |
35 | 6.49 | 2.53 | ||
45 | 6.48 | 2.60 | ||
55 | 6.47 | 2.69 |
In Hz.