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. Author manuscript; available in PMC: 2019 Jul 20.
Published in final edited form as: J Am Chem Soc. 2019 Jan 8;141(2):758–762. doi: 10.1021/jacs.8b11521

Figure 3.

Figure 3

Flexizyme-enabled benchtop biosynthesis of lactazole W2S, S11C. a) Sequence of designer precursor peptide. b) Proposed route to lactazole scaffolds. EICs for the hexathiazole and Dha-containing product of treatment with LynD/TbtE and H2O2 (c), and fully cyclized lactazole core (d).