Table 1. Thermal Data of PS Adducts.
| DSC heating |
DSC cooling |
TGA |
||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Tg/°C | aTrecrys/°C | ΔHrecrys (J g–1) | Tmelt/°C | ΔHmelt (J g–1) | Tsolid/°C | ΔHsolid (J g–1) | Tonset/°C | bTmax (°C) | cresidue/% | |
| POSS–PS | –4.2 | 323.4 | 338.8, 465.2 | 4.3 | ||||||
| VEIm–PS | 22.2 | 42.7, 79.9 | 17.52, 7.39 | 124.5 | –79.99 | 98.0 | 28.36 | 272.4 | 313.6 | 0.9 |
| MDIm–PS | 113.7 | 10.97 | 132.0 | –62.58 | 114.0 | 55.06 | 308.7 | 395.1 | 0.9 | |
| VDIm–PS | 120.9, 135.7 | –26.75, −10.20 | 104.8 | 47.59 | 278.5 | 319.4 | 9.3 | |||
a
Trecrys: temperature of recrystallization (Tonset).
b
Tmax: temperature of the maximum rate of degradation.
c
Residue at 800 °C under N2 flow at 10 °C min–1.