Table 2. Fluorescence Lifetimes (τ/ns), Relative Amplitude (A/%), and Rotational Correlation Time [r(t)/ns] for PS–Imidazolium Derivatives in CHCl3a.
| sample | τ1/ns | τ2/ns | A1 | A2 | r(t)/ns |
|---|---|---|---|---|---|
| bPS–Na | 3.2 ± 0.02 | 54.2 ± 0.3 | 10 | 90 | |
| TBA–PS | 1.7 ± 0.04 | 4.6 ± 0.02 | 40 | 60 | 1.04 ± 0.03 |
| MDIm–PS | 1.4 ± 0.05 | 4.7 ± 0.02 | 32 | 68 | 0.97 ± 0.05 |
| VDIm–PS | 1.6 ± 0.05 | 4.6 ± 0.02 | 35 | 65 | 1.02 ± 0.05 |
| VEIm–PS | 1.8 ± 0.05 | 4.7 ± 0.02 | 32 | 68 | 1.01 ± 0.08 |
| POSS–PS | 2.1 + 0.03 | 4.8 + 0.01 | 43 | 57 | 1.05 ± 0.05 |
| GF/VDIm–PS | 1.6 ± 0.03 | 3.7 ± 0.04 | 14 | 86 |
10 μM, T = 298 K, λex = 390 nm, λem = 450 nm.
H2O.