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. 2018 Dec 28;3(12):18811–18820. doi: 10.1021/acsomega.8b02961

Table 2. Fluorescence Lifetimes (τ/ns), Relative Amplitude (A/%), and Rotational Correlation Time [r(t)/ns] for PS–Imidazolium Derivatives in CHCl3a.

sample τ1/ns τ2/ns A1 A2 r(t)/ns
bPS–Na 3.2 ± 0.02 54.2 ± 0.3 10 90  
TBA–PS 1.7 ± 0.04 4.6 ± 0.02 40 60 1.04 ± 0.03
MDIm–PS 1.4 ± 0.05 4.7 ± 0.02 32 68 0.97 ± 0.05
VDIm–PS 1.6 ± 0.05 4.6 ± 0.02 35 65 1.02 ± 0.05
VEIm–PS 1.8 ± 0.05 4.7 ± 0.02 32 68 1.01 ± 0.08
POSS–PS 2.1 + 0.03 4.8 + 0.01 43 57 1.05 ± 0.05
GF/VDIm–PS 1.6 ± 0.03 3.7 ± 0.04 14 86  
a

10 μM, T = 298 K, λex = 390 nm, λem = 450 nm.

b

H2O.