Table 5. Synthesis of Thienoindoles (6m–q) from RC Adduct 5a and Differently Substituted Indoline-2-thiones 1^a.

entry	1, R	X	6	time (h)	% yieldb
1	1b, Et	H	6m	12	87
2	1c, nPr	H	6n	12	55
3	1d, Bn	H	6o	13	94
4	1e, Me	Cl	6p	5	44
5	1f, H	H	6q	7	44

^aReaction scale: 1a (0.75 mmol, 1.0 equiv), 5 (0.75 mmol, 1.0 equiv), K₂CO₃ (0.75 mmol, 1.0 equiv) in CH₃CN, and H₂O (97:3 v/v, 3 mL) at RT.

^bAfter silica-gel column chromatography.