Table 4. Effect of the Reaction Temperature and Time on the Catalytic Performance of the Pd Complexes^a.

entry	catalyst	cocatalyst	T (°C)	time (h)	conv.b (%)	HAc (%)	HYd (%)
1	1	AgOTf	80	25	97	68	4
2	1	AgOTf	80	4	79	57	4
3	1	AgSbF6	80	4	89	58	11
4	2	AgOTf	80	25	99	83	7
5	2	AgOTf	80	4	80	66	7
6	2	AgSbF6	40	4	48	24	4
7	2	AgSbF6	40	25	97	65	9
8	1	AgSbF6	40	4	43	41	4
9	1	AgSbF6	40	25	99	71	8

^aReaction conditions: 1 mmol mesitylamine, 1 mmol phenylacetylene, 0.01 mmol (1 mol %) catalyst, 2 mol % AgX.

^bAlkyne conversion.

^cYield in hydroamination product.

^dYield in hydration product.