Table 2. Xylose Conversion and Furfural Selectivity and Yield for H2SO4 and Heterogeneous Zeolites at Different Temperaturesa.
furfural |
|||||
---|---|---|---|---|---|
catalyst | temperature (K) | time (h) | xylose conversion (%) | selectivity (%) | yield (%) |
0.02 M H2SO4 | 423 | 6 | 35 | 66 | 23 |
443 | 6 | 82 | 62 | 51 | |
463 | 2 | 87 | 69 | 60 | |
SAPO-34/5A bead | 423 | 6 | 53 | 31 | 16 |
443 | 6* | 87 | 37 | 32 | |
463 | 3 | 95 | 47 | 45 | |
SAPO-34 powder | 423 | 6 | 27 | 31 | 8 |
443 | 6 | 80 | 43 | 34 | |
463 | 3 | 85 | 46 | 39 | |
SAPO-34C powder | 423 | 6 | 17 | 37 | 6 |
443 | 6* | 53 | 51 | 27 | |
463 | 3 | 57 | 54 | 31 | |
5A bead | 423 | 6 | 75 | 13 | 10 |
443 | 6 | 95 | 20 | 20 | |
463 | 3 | 97 | 21 | 21 | |
no catalyst | 423 | 6 | 10 | 69 | 7 |
443 | 6 | 41 | 51 | 21 | |
463 | 3 | 58 | 54 | 31 |
Reaction conditions: 2 wt % xylose, 4 mL H2O, and 0.02 M H2SO4 or 0.048 g of catalyst. Experimental error is ±4%, based on multiple trials of reactions marked with an asterisk.