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Thermal ellipsoid plot of 1 (50% level); hydrogens have arbitrary radii. A second chloride (2.326 Å from Ti, see text) has been removed for clarity. Selected bond distances (Å) and angles (deg): Ti1–O1, 1.8300(19); Ti1–Cl1, 2.4215(3); O1–C11, 1.419(2); Ti–Cp′ (ring centroid), 2.083 (ave); O1–Ti1–Cl1, 93.61(5); Ti1–O1–C11, 138.53(13); and Cp–Ti–Cp′, 130.9.
