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Thermal ellipsoid plot of 4 (50% level); hydrogens have arbitrary radii. Selected bond distances (Å) and angles (deg): Ti1–O1, 1.774(3); Ti1–Br1, 2.534(2); O1–C11, 1.414(5); Ti–Cp′ (ring centroid), 2.096 (ave); O1–Ti1–Br1, 84.67(16); Ti1–O1–C11, 175.8(3); and Cp–Ti–Cp′, 128.8.
