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. 2018 Oct 9;3(10):12868–12877. doi: 10.1021/acsomega.8b02320

Table 1. Screening of VLPC Catalysts in the Bromination of Naphthalene with NBS.

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entrya catalyst 3b entrya catalyst 3b
1 none 48 11 methylene blue 18
2 acridine orange 15 12 methylene green 77
3 azure A 31 13 Nile blue A 67
4 brilliant cresyl blue 27 14 pyronin Y 64
5 brilliant green 55 15 rhodamine 6G 61
6 DDQ 19 16 rhodamine B 60
7 eosin Y 0 17 rose bengal 87
8 erythrosine B 94 18 safranin O 54
9 fluorescein 58 19 thionin 71
10 9-mesityl-10-methylacridinium 75 20 [Ru(bpy)3]Cl2 0
a

Conditions: 0.25 mmol naphthalene, 0.25 mmol NBS, 0.0125 mmol catalyst, 3 mL MeCN, air, 20 °C, white light-emitting diode (LED), 24 h.

b

Gas chromatography (GC) yields calculated using adamantane as the internal standard.