Table 5. Substrate Scope of Arene Bromination.
Conditions A: 1 equiv. arene, 1.1 equiv. NBS, 0.1 equiv. (NH4)2S2O8, 0.01 equiv. erythrosine B [0.0017M], MeCN, air, 20 °C, white LED. All yields are isolated unless otherwise noted.
Conditions B: 2.2 equiv. NBS used. Yields are isolated.
GC yield calculated using adamantane as the internal standard.
Determined by 1H NMR integration using nitrobenzene as the internal standard.
Inseparable mixture of isomers.