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. 2018 Oct 18;3(10):13510–13523. doi: 10.1021/acsomega.8b01364

Table 4. Gas Diffusion Coefficients, D (108 cm2/s), Solubility Coefficients (S) in 10–2 cm3 (STP)/cm3 cmHg, Diffusivity Selectivity (αD), and Solubility Selectivity (αS) Values of the Polyimidesa,b.

  CO2
O2
N2
CH4
CO2/CH4
O2/N2
polymer D S D S D S D S αD αS αD αS
PI A 20.2 8.7 21.7 2.8 6.5 1.5 3.10 1.10 6.51 7.90 3.33 1.86
PI B 17.4 6.5 21.0 2.7 5.9 1.5 2.54 0.98 6.85 6.63 3.55 1.80
PI C 15.5 6.3 16.1 2.5 4.8 1.4 2.20 0.90 7.04 7.00 3.35 1.78
PI D 15.2 6.2 15.6 2.2 5.0 1.2 2.17 0.89 7.00 6.96 3.12 1.83
a

D is the gas diffusion coefficients in 10–8 cm2/s.

b

S is the gas solubility coefficients in 10–2 cm3 (STP)/cm3 cmHg (S = P/D).