Table 4. Gas Diffusion Coefficients, D (108 cm2/s), Solubility Coefficients (S) in 10–2 cm3 (STP)/cm3 cmHg, Diffusivity Selectivity (αD), and Solubility Selectivity (αS) Values of the Polyimidesa,b.
CO2 |
O2 |
N2 |
CH4 |
CO2/CH4 |
O2/N2 |
|||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
polymer | D | S | D | S | D | S | D | S | αD | αS | αD | αS |
PI A | 20.2 | 8.7 | 21.7 | 2.8 | 6.5 | 1.5 | 3.10 | 1.10 | 6.51 | 7.90 | 3.33 | 1.86 |
PI B | 17.4 | 6.5 | 21.0 | 2.7 | 5.9 | 1.5 | 2.54 | 0.98 | 6.85 | 6.63 | 3.55 | 1.80 |
PI C | 15.5 | 6.3 | 16.1 | 2.5 | 4.8 | 1.4 | 2.20 | 0.90 | 7.04 | 7.00 | 3.35 | 1.78 |
PI D | 15.2 | 6.2 | 15.6 | 2.2 | 5.0 | 1.2 | 2.17 | 0.89 | 7.00 | 6.96 | 3.12 | 1.83 |
D is the gas diffusion coefficients in 10–8 cm2/s.
S is the gas solubility coefficients in 10–2 cm3 (STP)/cm3 cmHg (S = P/D).