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. 2018 Jun 25;3(6):6820–6826. doi: 10.1021/acsomega.8b01207

Table 3. Substrate Scope for 2-Mercaptobenzothiazoles.

graphic file with name ao-2018-01207y_0005.jpg

entry 2 (R) 3 yield (%)a er
1 2a (H) 3a 99 89.5:10.5
2 2b (5-OMe) 3b 86 86:14
3 2c (5-OCF3) 3c 99 90.5:9.5
4 2d (5-Me) 3d 96 88.5:11.5
5 2e (6-Me) 3e 99 89.5:10.5
6 2f (5-Cl) 3f 61 90.5:9.5
7 2g (6-Cl) 3g 19 82.5:17.5
8 2h (5-F) 3h 92 89.5:10.5
9 2i (5-CN) 3i 51 87:13
10 2j (5-NO2) 3j 32 81:19
a

Isolated yield for 0.3 mmol scale reactions.