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. 2017 Oct 16;2(10):6728–6740. doi: 10.1021/acsomega.7b00321

Table 1. UV–Visible Spectral (Electronic) Information of the (Acetonedicarboxylato)copper Solutiona.

wavelength (nm) molar absorbance (M–1 cm–1)    
242 N.D.b π → π* H2Acdica(enol)1– and [CuII(H2Acdica)enol]1+
246 6970 π → π* [CuII(HAcdica)enol]0
400 151c 2p → d (O)π → CuII
757 60.7c d–d [CuII(HAcdica)enol]0
a

Note: 246 nm data were obtained at pH 7.25 from Figure 2a.

b

This molar absorbance was not determined because the species may be a mixture.

c

This data was obtained from Figure S4 at pH 7.00.