Table 5. Values of Kads and ΔG°ads Obtained from the Langmuir Adsorption Isotherm Graphs for the Studied Inhibitors on Mild Steel in 5% HCl at 303 K.
inhibitor | method | slope | Kads (ppm/mol) | –ΔG°ads (kJ mol–1) |
---|---|---|---|---|
ZnO/PEG | EIS | 1.390 | 0.0416 | 26.80 |
PDP | 1.644 | 0.0224 | 25.23 | |
LPR | 1.537 | 0.0231 | 25.31 | |
ZnO/PVP | EIS | 1.082 | 0.0384 | 26.59 |
PDP | 1.316 | 0.0345 | 26.32 | |
LPR | 1.415 | 0.0748 | 28.27 | |
ZnO/PAN | EIS | 1.018 | 0.0044 | 21.12 |
PDP | 1.066 | 0.0069 | 22.26 | |
LPR | 1.122 | 0.0071 | 22.35 |