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ORTEP drawings for (top) V(NAd)Cl2(L) (1), (middle) V(NC6H5)Cl2(L) (2), and (bottom) V(NAr)Cl2(L) (3) [Ad = 1-adamantyl, Ar = 2,6-Me2C6H3; L = 2-(2′-benzimidazolyl)-6-methylpyridine]. Thermal ellipsoids are drawn at the 50% probability level, and H atoms are omitted for clarity.
