. 2017 Dec 7;2(12):8689–8696. doi: 10.1021/acsomega.7b01566

Table 3. Scope of the Fluoranthene Synthesis under Both Homogeneous and Heterogeneous Catalytic Conditions^a.

Reaction conditions: method A: 1.0 equiv of 5, 1.15 equiv of arylboronic acid or ester, 4.0 equiv of KOAc, 5 mol % of Pd(dppf)Cl₂, DMSO, 90 or 110 °C, N₂, 24 h. Method B: 1.0 equiv of 5, 1.15 equiv of arylboronic acid or ester, 5.0 equiv of NaOAc, 4.0 mg of rGO-CuPd nanocatalyst (1.8 mol % Pd loading), 120 °C, 24 h.

T = 90 °C for method A.

T = 110 °C for method A.

Table 3. Scope of the Fluoranthene Synthesis under Both Homogeneous and Heterogeneous Catalytic Conditionsa.

Table 3. Scope of the Fluoranthene Synthesis under Both Homogeneous and Heterogeneous Catalytic Conditions^a.