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. 2017 Dec 8;2(12):8796–8802. doi: 10.1021/acsomega.7b00909

Table 2. TOFs for the Suzuki Coupling Reaction in the Flow System Using Pd/MPGsa and Diffusion Coefficients of the Substrates and Product in the Gel Network.

  D in gel network (×10–10 m2 s–1)b
TOF (h–1)
entry 1 2 3  
Pd/MPG1 5.8 8.0 3.5 27.4
Pd/MPG2 4.9 3.9 2.1 16.1
Pd/MPG3 1.2 3.2 1.2 7.8
a

Reaction conditions: 1 (10 mmol L–1) and 2 (11 mmol L–1, 1.1 equiv) in aqueous Na2CO3 solutions (11 mmol L–1, 1.1 equiv), 30 °C. BIS contents: 5 mol % for gels.

b

Estimated using nonporous gels with the same monomer composition as MPGs.