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(A) Intensity–time trajectories following the reaction of 4.5 μM of compound 3 and 1.09 M methanol (MeOH), ethanol (EtOH), butanol (BuOH), ethylene glycol (EtyGly), water (H2O), and ethanedithiol (EtSH2) at 21 °C in acetonitrile supplemented with 0.333 mM of p-TsOH. (B) Apparent rate constants for various nucleophiles tested were obtained from fitting the intensity–time trajectories in panel (A) with eq 2. Error bars were obtained from the error of the fitting with eq 2.
