Table 2. Pd-Catalyzed Decarbonylative Borylation of Amidesa.
Conditions: amide (1.0 equiv), B2pin2 (1.2 equiv), Pd(TFA)2 (5 mol %), PCy3HBF4 (20 mol %), Na2CO3 (1.0 equiv), dioxane (0.25 M), 150 °C, and 15 h. Isolated yields. See the Supporting Information for full details.