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Comparison between the apparent (a) Ω(13C) and (b) κ(13C) of CO2 (open red circles) and CO (solid black squares) in α-Zn3(HCOO)6 at various temperatures. The vertical dashed line marks the temperature (ca. 293 K) where the Ω and κ trends begin to reverse for CO2. The Ω and κ values were obtained from analytical simulations as shown in Figures 3 and 7. The measured values can be found in Tables S10 and S11.
