Table 2. Numerical Analysis of NIR PL Spectraa.
catechin concentration [mg/mL] | initial | H2O2, 2 min | H2O2, 20 min | catechin, 2 min | catechin, 10 min | catechin, 20 min | catechin, 30 min | ||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
15 | (9, 4) | 0.67 ± 0.10 | 100.0 | 0.14 ± 0.03 | 20.9 | 0.09 ± 0.02 | 13.4 | 1.68 ± 0.20 | 250.7 | 1.64 ± 0.21 | 244.8 | 1.62 ± 0.23 | 241.8 | 1.56 ± 0.21 | 232.8 |
(8, 6) | 0.15 ± 0.02 | 100.0 | 0.03 ± 0.01 | 20.0 | 0.02 ± 0.01 | 13.3 | 0.67 ± 0.09 | 446.7 | 0.66 ± 0.09 | 440.0 | 0.65 ± 0.10 | 433.3 | 0.63 ± 0.09 | 420.0 | |
(8, 7) | 0.07 ± 0.01 | 100.0 | 0.04 ± 0.01 | 57.1 | 0.04 ± 0.00 | 57.1 | 0.28 ± 0.04 | 400.0 | 0.29 ± 0.03 | 414.3 | 0.28 ± 0.04 | 400.0 | 0.27 ± 0.04 | 385.7 | |
1.5 | (9, 4) | 0.74 ± 0.15 | 100.0 | 0.14 ± 0.04 | 18.9 | 0.08 ± 0.01 | 10.8 | 1.96 ± 0.25 | 264.9 | 1.77 ± 0.26 | 239.2 | 1.59 ± 0.28 | 214.9 | 1.44 ± 0.31 | 194.6 |
(8, 6) | 0.17 ± 0.04 | 100.0 | 0.03 ± 0.01 | 17.6 | 0.03 ± 0.01 | 17.6 | 0.72 ± 0.11 | 423.5 | 0.60 ± 0.11 | 352.9 | 0.51 ± 0.12 | 300.0 | 0.44 ± 0.12 | 258.8 | |
(8, 7) | 0.08 ± 0.01 | 100.0 | 0.04 ± 0.01 | 50.0 | 0.04 ± 0.00 | 50.0 | 0.29 ± 0.04 | 362.5 | 0.23 ± 0.04 | 287.5 | 0.19 ± 0.05 | 237.5 | 0.16 ± 0.04 | 200.0 | |
0.3 | (9, 4) | 0.59 ± 0.03 | 100.0 | 0.11 ± 0.01 | 18.6 | 0.07 ± 0.00 | 11.9 | 1.42 ± 0.01 | 240.7 | 0.59 ± 0.04 | 100.0 | 0.22 ± 0.01 | 37.3 | 0.14 ± 0.01 | 23.7 |
(8, 6) | 0.13 ± 0.01 | 100.0 | 0.03 ± 0.00 | 23.1 | 0.02 ± 0.01 | 15.4 | 0.43 ± 0.01 | 330.8 | 0.13 ± 0.01 | 100.0 | 0.04 ± 0.00 | 30.8 | 0.03 ± 0.01 | 23.1 | |
(8, 7) | 0.06 ± 0.00 | 100.0 | 0.04 ± 0.00 | 66.7 | 0.04 ± 0.00 | 66.7 | 0.15 ± 0.00 | 250.0 | 0.06 ± 0.01 | 100.0 | 0.05 ± 0.00 | 83.3 | 0.04 ± 0.01 | 66.7 | |
0.15 | (9, 4) | 0.76 ± 0.18 | 100.0 | 0.14 ± 0.04 | 18.4 | 0.08 ± 0.02 | 10.5 | 0.49 ± 0.11 | 64.5 | 0.11 ± 0.00 | 14.5 | 0.09 ± 0.01 | 11.8 | 0.09 ± 0.01 | 11.8 |
(8, 6) | 0.18 ± 0.05 | 100.0 | 0.03 ± 0.01 | 16.7 | 0.03 ± 0.00 | 16.7 | 0.11 ± 0.03 | 61.1 | 0.03 ± 0.01 | 16.7 | 0.02±0.01 | 11.1 | 0.03 ± 0.00 | 16.7 | |
(8, 7) | 0.08 ± 0.02 | 100.0 | 0.05 ± 0.01 | 62.5 | 0.04 ± 0.01 | 50.0 | 0.07 ± 0.00 | 87.5 | 0.04 ± 0.01 | 50.0 | 0.04 ± 0.01 | 50.0 | 0.04 ± 0.00 | 50.0 | |
0.015 | (9, 4) | 0.69 ± 0.15 | 100.0 | 0.15 ± 0.05 | 21.7 | 0.08 ± 0.02 | 11.6 | 0.11 ± 0.04 | 15.9 | 0.08 ± 0.04 | 11.6 | 0.08 ± 0.02 | 11.6 | 0.07 ± 0.02 | 10.1 |
(8, 6) | 0.16 ± 0.03 | 100.0 | 0.04 ± 0.01 | 25.0 | 0.03 ± 0.01 | 18.8 | 0.03 ± 0.01 | 18.8 | 0.02 ± 0.01 | 12.5 | 0.02 ± 0.01 | 12.5 | 0.02 ± 0.01 | 12.5 | |
(8, 7) | 0.07 ± 0.01 | 100.0 | 0.04 ± 0.01 | 57.1 | 0.04 ± 0.00 | 57.1 | 0.04 ± 0.01 | 57.1 | 0.04 ± 0.01 | 57.1 | 0.04 ± 0.01 | 57.1 | 0.04 ± 0.01 | 57.1 | |
0.0015 | (9, 4) | 0.84 ± 0.03 | 100.0 | 0.18 ± 0.04 | 21.4 | 0.10 ± 0.02 | 11.9 | 0.11 ± 0.03 | 13.1 | 0.10 ± 0.02 | 11.9 | 0.09 ± 0.02 | 10.7 | 0.09 ± 0.02 | 10.7 |
(8, 6) | 0.19 ± 0.01 | 100.0 | 0.05 ± 0.01 | 26.3 | 0.03 ± 0.00 | 15.8 | 0.03 ± 0.00 | 15.8 | 0.03 ± 0.00 | 15.8 | 0.02 ± 0.01 | 10.5 | 0.02 ± 0.01 | 10.5 | |
(8, 7) | 0.08 ± 0.01 | 100.0 | 0.04 ± 0.01 | 62.5 | 0.05 ± 0.00 | 62.5 | 0.04 ± 0.00 | 50.0 | 0.05 ± 0.01 | 62.5 | 0.04 ± 0.00 | 50.0 | 0.05 ± 0.00 | 62.5 |
Excitation wavelength was 730 nm.