Table 4. Adsorption Thermodynamics Parameters for Hg(II)-/SF-/BCB-NRCBD.
C0 (ppm) | T (K) | –ΔG0 (kJ mol–1) | –ΔH0 (kJ mol–1) | –ΔS0 (J mol–1 K–1) |
---|---|---|---|---|
5 | 293 | 8.96/10.75/9.71 | 12.77/37.92/5.33 | 13.01/158.90/54.92 |
303 | 8.84/11.33/10.31 | |||
313 | 8.66/11.86/11.36 | |||
323 | 8.59/12.40/12.29 | |||
10 | 293 | 8.40/10.47/7.98 | 15.30/42.43/7.09 | 23.87/171.43/59.92 |
303 | 7.97/11.06/9.40 | |||
313 | 7.71/11.66/10.94 | |||
323 | 7.71/12.27/13.21 | |||
15 | 293 | 7.52/10.21/6.95 | 14.53/33.49/6.90 | 24.28/137.73/58.44 |
303 | 7.03/10.81/8.17 | |||
313 | 6.90/11.42/9.45 | |||
323 | 6.77/11.95/11.14 | |||
25 | 293 | 6.89/9.64/7.77 | 13.92/15.86/9.49 | 24.09/80.36/65.30 |
303 | 6.55/10.26/8.41 | |||
313 | 6.40/11.01/9.20 | |||
323 | 6.15/11.57/10.20 | |||
35 | 293 | 6.49/9.03/8.41 | 10.74/9.62/10.97 | 14.69/61.50/68.29 |
303 | 6.20/9.71/9.02 | |||
313 | 6.15/10.45/9.63 | |||
323 | 6.02/11.05/10.25 | |||
40 | 293 | 5.55/8.52/8.66 | 9.48/10.12/11.82 | 13.51/64.13/69.47 |
303 | 5.34/9.23/9.32 | |||
313 | 5.22/9.95/9.96 | |||
323 | 5.15/10.60/10.58 |