Table 3. Electroanalytical Parameters for Silica-Modified GC Electrodes of Different Types. For Experimental Conditions, See Figure 3.
sensitivity (A/M) |
DL (μM) |
linear domain (μM) |
R2/no. of points |
|||||
---|---|---|---|---|---|---|---|---|
electrode | pH 6 | pH 4.4 | pH 6 | pH 4.4 | pH 6 | pH 4.4 | pH 6 | pH 4.4 |
GC/Nafion | 0.013 ± 0.001 | 0.165 ± 0.049 | 4.79 | 4.14 | 0–100 | 0–10 | 0.9987/12 | 0.9914/7 |
GC/SBA-15/Nafion | 0.377 ± 0.007 | 0.564 ± 0.023 | 0.97 | 1.10 | 0–20 | 0–10 | 0.9979/8 | 0.9920/7 |
GC/SBA-15-NH2/Nafion | 1.520 ± 0.020 | 1.462 ± 0.052 | 0.36 | 0.73 | 0–10 | 0–8 | 0.9991/7 | 0.9950/6 |
GC/MCM-41/Nafion | 0.992 ± 0.047 | 2.487 ± 0.063 | 0.97 | 0.70 | 0–8 | 0–10 | 0.9912/6 | 0.9968/7 |
GC/MCM-41-NH2/Nafion | 0.765 ± 0.020 | 2.300 ± 0.121 | 0.71 | 0.76 | 0–10 | 0–6 | 0.9909/7 | 0.9901/5 |