Table 1. Thermodynamic and Kinetic Parameters Derived from DSC Traces.

		thermodynamics			kinetics
samples	Tp (K)	ΔH≠ (kJ mol–1)	ΔG≠ (kJ mol–1)	ΔS≠ (J mol–1 K–1)	EK (kJ mol–1)	ln AK	k (s–1)
pure AP	739.05	111.06	192.89	110.72	117.21	18.05	0.36
[90% AP + 10% (nano TAGN)]	557.25	147.70	130.36	31.13	152.34	34.83	7.00
low-temperature reaction	475.95	133.24	118.48	31.02	137.19	34.66	0.99