Table 2. Thermodynamic and Kinetic Parameters Derived from DSC Traces.

		thermodynamics			kinetics
samples	Tp (K)	ΔH≠ (kJ mol–1)	ΔG≠ (kJ mol–1)	ΔS≠ (J mol–1 K–1)	EK (kJ mol–1)	ln AK	k (s–1)
pure AN	553.3	156.80	138.66	32.79	161.40	35.02	0.934
[90% AN + 10% (nano TAGN)]	550.3	147.51	137.75	9.41	147.51	32.2	0.963
nano TAGN	511.4	158.69	127.23	61.52	162.94	38.4	1.082
raw TAGN	504.7	166.01	124.80	41.21	170.20	40.81	1.270