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. 2019 Mar 25;4(3):5805–5817. doi: 10.1021/acsomega.9b00145

Table 7. Effective Rate Coefficients (cm3 molecule–1 s–1) of Monohydrated CH3CH2OH + OH Reaction over the Temperature Range of 216.7–425.0 Ka.

T (K) kC1a1-W kC1b-W kC1c1-W
216.7 1.6 × 10–17 8.1 × 10–19 3.5 × 10–14
223.3 2.3 × 10–17 1.3 × 10–18 4.0 × 10–14
236.3 4.3 × 10–17 3.0 × 10–18 5.0 × 10–14
249.3 7.4 × 10–17 6.3 × 10–18 6.1 × 10–14
262.2 1.2 × 10–16 1.2 × 10–17 7.3 × 10–14
275.2 1.8 × 10–16 2.2 × 10–17 8.4 × 10–14
288.2 2.7 × 10–16 3.7 × 10–17 9.4 × 10–14
298.2 3.5 × 10–16 5.4 × 10–17 1.0 × 10–13
325.0 6.5 × 10–16 1.3 × 10–16 1.2 × 10–13
425.0 2.8 × 10–15 1.0 × 10–15 1.6 × 10–13
a

kC3a1-W, kC3b-W, and kC3c1-W are the rate coefficients of path (a1-W), path (b-W), and path (c1-W), respectively, via channel 3 in the water-assisted reaction, and kC3-W is the sum of kC3a1-W, kC3b-W, and kC3c1-W at temperature T.