Table 7. Effective Rate Coefficients (cm3 molecule–1 s–1) of Monohydrated CH3CH2OH + •OH Reaction over the Temperature Range of 216.7–425.0 Ka.
| T (K) | kC1a1-W′ | kC1b-W′ | kC1c1-W′ |
|---|---|---|---|
| 216.7 | 1.6 × 10–17 | 8.1 × 10–19 | 3.5 × 10–14 |
| 223.3 | 2.3 × 10–17 | 1.3 × 10–18 | 4.0 × 10–14 |
| 236.3 | 4.3 × 10–17 | 3.0 × 10–18 | 5.0 × 10–14 |
| 249.3 | 7.4 × 10–17 | 6.3 × 10–18 | 6.1 × 10–14 |
| 262.2 | 1.2 × 10–16 | 1.2 × 10–17 | 7.3 × 10–14 |
| 275.2 | 1.8 × 10–16 | 2.2 × 10–17 | 8.4 × 10–14 |
| 288.2 | 2.7 × 10–16 | 3.7 × 10–17 | 9.4 × 10–14 |
| 298.2 | 3.5 × 10–16 | 5.4 × 10–17 | 1.0 × 10–13 |
| 325.0 | 6.5 × 10–16 | 1.3 × 10–16 | 1.2 × 10–13 |
| 425.0 | 2.8 × 10–15 | 1.0 × 10–15 | 1.6 × 10–13 |
kC3a1-W, kC3b-W, and kC3c1-W are the rate coefficients of path (a1-W), path (b-W), and path (c1-W), respectively, via channel 3 in the water-assisted reaction, and kC3-W is the sum of kC3a1-W, kC3b-W, and kC3c1-W at temperature T.