Table 8. Ratios of Effective Rate Coefficients of Hydrated Reactions to the Corresponding Rate Coefficients of the Bared CH3CH2OH + •OH Reactions over the Temperature Range of 216.7–425.0 K.
| T (K) | kC1a1-W′/ka | kC4a1-WW′/ka | kC1b-W′/kb | kC4b-WW′/kb | kC1c1-W′/kc | kC4c1-WW′/kc |
|---|---|---|---|---|---|---|
| 216.7 | 4.9 × 10–5 | 1.8 × 10–6 | 2.9 × 10–5 | 6.1 × 10–8 | 1.3 × 10–4 | 8.3 × 10–8 |
| 223.3 | 6.8 × 10–5 | 1.9 × 10–6 | 4.1 × 10–5 | 7.7 × 10–8 | 1.7 × 10–4 | 1.0 × 10–7 |
| 236.3 | 1.2 × 10–4 | 2.0 × 10–6 | 7.7 × 10–5 | 1.1 × 10–7 | 2.7 × 10–4 | 1.5 × 10–7 |
| 249.3 | 1.8 × 10–4 | 2.0 × 10–6 | 1.3 × 10–4 | 1.6 × 10–7 | 4.0 × 10–4 | 2.1 × 10–7 |
| 262.2 | 2.8 × 10–4 | 2.0 × 10–6 | 2.1 × 10–4 | 2.0 × 10–7 | 5.5 × 10–4 | 2.6 × 10–7 |
| 275.2 | 4.0 × 10–4 | 2.0 × 10–6 | 3.3 × 10–4 | 2.5 × 10–7 | 7.4 × 10–4 | 3.2 × 10–7 |
| 288.2 | 5.4 × 10–4 | 1.9 × 10–6 | 4.8 × 10–4 | 3.0 × 10–7 | 9.6 × 10–4 | 3.8 × 10–7 |
| 298.2 | 6.8 × 10–4 | 1.8 × 10–6 | 6.2 × 10–4 | 3.3 × 10–7 | 1.1 × 10–3 | 4.2 × 10–7 |
| 325.0 | 1.1 × 10–3 | 1.5 × 10–6 | 1.1 × 10–3 | 4.1 × 10–7 | 1.7 × 10–3 | 5.2 × 10–7 |
| 425.0 | 3.4 × 10–3 | 7.0 × 10–7 | 4.4 × 10–3 | 4.8 × 10–7 | 3.8 × 10–3 | 5.9 × 10–7 |