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. 2019 Feb 8;4(2):2883–2892. doi: 10.1021/acsomega.8b03242

Table 3. Coefficients in Equation 3 for Water–Methanol and Water–Ethanol Partitions, SP = log P; Composition of Mixtures Given as Volume %.

  coefficients
solvents c e s a b v j+ j
methanol 0.276 0.334 –0.714 0.243 –3.320 3.549 –2.609 3.027
95% 0.270 0.278 –0.520 0.230 –3.368 3.365 –2.661 2.909
90% 0.258 0.250 –0.452 0.229 –3.206 3.175 –2.629 2.707
80% 0.172 0.197 –0.319 0.241 –2.912 2.842 –2.540 2.421
70% 0.098 0.192 –0.260 0.266 –2.558 2.474 –2.267 2.164
60% 0.053 0.207 –0.238 0.272 –2.157 2.073 –1.978 1.872
50% 0.023 0.223 –0.222 0.264 –1.747 1.662 –1.588 1.569
40% 0.020 0.222 –0.205 0.218 –1.329 1.259 –1.329 1.259
30% 0.016 0.187 –0.172 0.165 –0.953 0.898 –0.823 0.930
20% 0.022 0.142 –0.138 0.088 –0.574 0.559 –0.465 0.599
10% 0.012 0.072 –0.081 0.026 –0.249 0.266 –0.185 0.287
ethanol 0.222 0.471 –1.035 0.326 –3.596 3.857 –3.170 3.085
96% 0.238 0.353 –0.833 0.297 –3.533 3.724 –3.020 2.970
95% 0.239 0.328 –0.795 0.294 –3.514 3.697 –2.985 2.943
90% 0.243 0.213 –0.575 0.262 –3.450 3.545 –2.794 2.837
80% 0.172 0.175 –0.465 0.260 –3.212 3.323 –2.466 2.722
70% 0.063 0.085 –0.368 0.311 –2.936 3.102 –2.203 2.550
60% –0.040 0.138 –0.335 0.293 –2.675 2.812 –1.858 2.394
50% –0.142 0.124 –0.252 0.251 –2.275 2.415 –1.569 2.051
40% –0.221 0.131 –0.159 0.171 –1.809 1.918 –1.271 1.676
30% –0.269 0.107 –0.098 0.133 –1.316 1.414 –0.941 1.290
20% –0.252 0.042 –0.040 0.096 –0.823 0.916 –0.677 0.851
10% –0.173 –0.023 –0.001 0.065 –0.372 0.454 –0.412 0.401