Table 4. Calculated ΔG^≠ and k at the B3LYP/6-311G(d,p) Level of Theory at 298.15 K in the Gas Phase^a.

reactions	ΔG≠ (kcal·mol–1)	k (L·mol–1·s–1)
1–C3–H + HOO·	9.6	3.13 × 107
1–O4′–H + HOO·	10.4	4.10 × 106
9–C4–H + HOO·	13.9	7.23 × 103
9–O7–H + HOO·	4.4	1.02 × 1010 (2.07 × 109)*
9–O4′–H + HOO·	5.2	5.12 × 109 (1.72 × 109)*

^aAsterisk (*): the apparent rate constants k_app.