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. 2019 Jun 27;4(6):11229–11236. doi: 10.1021/acsomega.9b01287

Table 1. Summary of Data for Diblock Copolymer Obtained by SEC and 1H NMR.

polymer [AzoMA]/[BA] in feed Mn (kDa) polydispersity indexa [AzoMA]/[BA]b polymerization degree fPDMAc
PDMA   11.9a 1.06   120  
PDMA-b-P(AzoMA5.2-r-BA) 2/98 31.2b 1.15 5.2/94.8 120–142 0.38
PDMA-b-P(AzoMA11.0-r-BA) 4/96 32.1b 1.17 11.0/89.0 120–150 0.37
PDMA-b-P(AzoMA13.8-r-BA) 6/94 31.9b 1.22 13.8/86.2 120–135 0.37
a

Characterized by SEC (mobile phase: N,N-dimethylformamide containing 0.1 mol/L lithium bromide).

b

Calculated from 1H NMR.

c

Calculated form Materials Studio (ρPDMA = 1.096 ρP(AzoMA-r-BA) = 1.094).