Table 1. Molecular Weights and Compositions of PS–PEO–PS Block Copolymers.
samples | Mn,PEOa (g mol–1) | Mn,PSb (g mol–1) | Mn,totalc (g mol–1) | wt % PEO/PS | PDId |
---|---|---|---|---|---|
SES-1 | 8000 | 1560 × 2 | 11 120 | 71.9:28.1 | 1.26 |
SES-2 | 8000 | 2500 × 2 | 13 000 | 61.5:38.5 | 1.1 |
SES-3 | 8000 | 4800 × 2 | 17 600 | 45.5:54.5 | 1.23 |
SES-4 | 8000 | 10 400 × 2 | 28 800 | 27.7:72.3 | 1.23 |
SES-5 | 8000 | 24 250 × 2 | 56 500 | 16.5:83.5 | 1.33 |
Mn,PEO provided by the supplier.
Mn,PS was determined by NMR.
Mn,total was the sum of Mn,PEO and Mn,PS.
PDI was obtained from GPC using tetrahydrofuran (THF) as the mobile phase and PS as the standard sample.