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. 2019 Jun 21;4(6):10854–10865. doi: 10.1021/acsomega.9b01509

Table 2. Negishi Coupling of Zinc Reagent 8 with Vinyl Bromides.

entry substrate R1 R2 R3 product yield (%)
1 12 Me H H 16 84
2 13 H Me Me 17 95
3 (E)-14 Me Me H (E)-18 68
4 (Z)-14 Me H Me (Z)-18 72
5 (E,Z)-14 Me Me/H (E,Z)-18 88
6 15 (CH2)2 H 19 79