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. 2019 Jun 21;4(6):10854–10865. doi: 10.1021/acsomega.9b01509

Table 3. Radical Hydrofluorination of Unsaturated Substrates.

entry substrate product yield (%)
1 1a 2a 64
2 1b 2b 64
3 1c 2c 70
4 1d 2d 65
5 10 23 54
6 11 24 0 (64)a
7 16 25 84
8 ent-16 ent-25 88
9 17 26 75
10 18 27 63
11 19 28 81
12 20 29 73
13 21 26 62
14 22 30 91
a

Reaction carried out by increasing the molar equivalents of Fe(III) and Selectfluor and by the dropwise addition of a solution of NaBH4 (in 0.1 M NaOH).