Table 1.
Composite | λex/nm | λem/nm | Emission Quantum Yield/% | Lifetime/µs |
---|---|---|---|---|
[RuII(bpy)3](1)2 | 450 | 600 | 8.4 | 0.68 |
[RuII(bpy)3](2)2 | 416 | 599 | 9.0 | 0.82 |
[RuII(bpy)3](3)2 | 420 | 599 | 7.7 | 0.74 |
[RuII(bpy)3](4)2 | 446 | 601 | 9.0 | 0.79 |
[RuII(bpy)3](5)2 | 448 | 602 | 8.9 | 0.78 |
[RuII(bpy)3](6)2 | 435 | 601 | 8.8 | 0.72 |
[RuII(bpy)3]Cl2 1 | 450 [71] | 608 [71] | 9.5 [71] | 0.89 [73] |
1 in acetonitrile.