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. Author manuscript; available in PMC: 2019 Aug 20.
Published in final edited form as: Inorg Chem. 2018 Aug 2;57(16):9794–9806. doi: 10.1021/acs.inorgchem.8b01529

Table 3.

BDE Values for [CuOH2]2+ Complexes

supporting ligand solvent BDE (kcal/mol) ref
SO3L4− DFB ∼91a this work
H2O ∼87 this work
NMe3L DFB ∼91.5a this work
H2O ∼91 this work
pyrL2− THF 90 ± 3 4
NO2L2− DFB 91 ± 3 4
pipL2− THF 88 ± 3 4
a

Approximate value, see text.