| Crystal data |
| Chemical formula |
C36H34N2O4P2
|
C14H30N2O8P2
|
|
M
r
|
620.59 |
416.34 |
| Crystal system, space group |
Monoclinic, C2/c
|
Orthorhombic, P
b
c
a
|
| Temperature (K) |
173 |
173 |
|
a, b, c (Å) |
13.0352 (2), 14.1348 (4), 17.0471 (4) |
8.9401 (1), 15.0535 (2), 15.7314 (3) |
| α, β, γ (°) |
90, 90.217 (2), 90 |
90, 90, 90 |
|
V (Å3) |
3140.90 (13) |
2117.13 (5) |
|
Z
|
4 |
4 |
| Radiation type |
Cu Kα |
Cu Kα |
| μ (mm−1) |
1.60 |
2.23 |
| Crystal size (mm) |
0.38 × 0.11 × 0.08 |
0.34 × 0.23 × 0.06 |
| |
| Data collection |
| Diffractometer |
Bruker APEXII CCD |
Bruker APEXII CCD |
| Absorption correction |
Multi-scan (SADABS; Bruker, 2013 ▸) |
Multi-scan (SADABS; Bruker, 2013 ▸) |
|
T
min, T
max
|
0.617, 0.754 |
0.612, 0.754 |
| No. of measured, independent and observed [I > 2σ(I)] reflections |
16825, 3022, 2543 |
10282, 2057, 1839 |
|
R
int
|
0.050 |
0.028 |
| (sin θ/λ)max (Å−1) |
0.617 |
0.617 |
| |
| Refinement |
|
R[F
2 > 2σ(F
2)], wR(F
2), S
|
0.041, 0.117, 1.03 |
0.035, 0.093, 1.05 |
| No. of reflections |
3022 |
2057 |
| No. of parameters |
204 |
154 |
| No. of restraints |
0 |
20 |
| H-atom treatment |
H atoms treated by a mixture of independent and constrained refinement |
H atoms treated by a mixture of independent and constrained refinement |
| Δρmax, Δρmin (e Å−3) |
0.33, −0.27 |
0.21, −0.27 |
