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(a) Concept of redox reversible cofactor binding. (b) Structure of cofactor 6 inspired from “azotochelin” the siderophore; crystal structure of the 6·CeuE highlighting the binding of H227 to Ir(III). (c) Selected results for the benchmark reduction to salsolidine 3. Reproduced with permission from ref (30). Copyright 2018 Nature Publishing Group.
