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. 2019 Jul 16;15:1581–1591. doi: 10.3762/bjoc.15.162

Table 1.

Intramolecular hydrogen bonds – temperature coefficient -dδ/dT [ppb/K] in DMSO.

Amide proton Glycopeptide

3 4

Ala1 5.6 5.1
Ala2 4.3 5.1
Thr3 4.8 4.8
GalNAc 5.2 5.8
Ala4 3.5 1.4
Ala5 7.6 8.4
CNMea 6.4 6.3

aCNMe–HN of C-terminal group.