Table 2.
Optimization of reaction conditions.
| Entry | Photocatalyst (Nanoassemblies) | Solvent | Time | Yield% |
|---|---|---|---|---|
| 1 | TETPY | ACN | 6 h | 82 |
| 2a | TETPY | ACN | 6 h | 85 |
| 3b | TETPY | ACN | 6 h | 68 |
| 4 | CNDIPY | ACN | 6 h | 85 |
| 5b | CNDIPY | ACN | 6 h | 65 |
| 6 | DIPY | ACN | 6 h | 45 |
| 7 | TETPY | CH2Cl2 | 6 h | 59 |
| 8 | TETPY | ACN:H2O(1:1) | 6 h | 30 |
| 9 | TETPY | DMSO | 6 h | 30 |
| 10 | TETPY | THF | 6 h | 45 |
| 11c | — | ACN | 6 h | NR |
| 12d | TETPY | ACN | 6 h | NR |
| 13e | TETPY | ACN | 6 h | NR |
anatural sunlight, bIsolated form, cNo photocatalyst, dNo light, eInert atmosphere, NR No reaction.