Table 3.
Sugar Residue | Chemical Shifts (δ, ppm) | ||||||
---|---|---|---|---|---|---|---|
H-1 C-1 | H-2 C-2 | H-3 C-3 | H-4 C-4 | H-5 C-5 | H-6 C-6 | ||
→2)-α-l-Rhap4NAc-(1→ | A | 5.18 | 4.16 | 4.07 | 3.93 | 3.85 | 1.21 |
101.7 | 78.3 | 69.2 | 54.3 | 69.7 | 18.2 | ||
→2)-α-l-Rhap4NAc-(1→ | B | 5.04 | 3.81 | 4.01 | 3.87 | 3.91 | 1.22 |
102.1 | 79.8 | 69.2 | 54.3 | 69.6 | 18.2 | ||
→3)-α-l-RhapNAc-(1→ | C | 5.00 | 3.87 | 3.93 | 4.00 | 3.92 | 1.24 |
103.3 | 70.7 | 78.3 | 53.2 | 69.5 | 18.2 | ||
→3)-α-l-Rhap4NAc-(1→ | D | 4.97 | 4.20 | 3.99 | 3.94 | 3.92 | 1.24 |
103.5 | 70.2 | 78.4 | 53.2 | 69.5 | 18.2 |
Chemical shifts for NAc are δH 2.07 and δC 23.4 (CH3) and 176.0 (CO).